3.a) Carbon tetrachloride is an organic compound with the chemical formula CCl4. It is a
colorless liquid with a “sweet” smell.
i.
...
quid with a “sweet” smell.
i. Using the ground state electron configuration and excited state electron
configuration explain the hybridization of the central Carbon (C) atom. (7 Marks)
ii. Identify the orbitals that overlap to form the C-Cl bond. Draw a diagram to show
the orbital overlap. (3 Marks)
iii. What is the bond angle of CCl4? (1 Mark)
b) Consider a Fluorine atom (F) and a Fluorine anion (F-). Which of these two species would
you expect to have a larger radius? Explain your answer. (5 Marks)
c) Explain why the first ionization energy of Aluminum (Al) is less than that of Magnesium
(Mg). (4 Marks)
d) Assume the atom Oxygen(O) can form both cationic(O+) and anionic(O-) species. Place
the following species in order of increasing first ionization energy, starting with the lowest.
O+, O, O-
(5 Marks)
4.
a) Sea water contains roughly 28.0 g of NaCl per liter. (NaCl molar mass = 58.44 gmol-1).
i. Calculate the number of moles of NaCl in a liter of sea water. (2 Marks)
ii. Calculate the molarity of NaCl in sea water. (4 Marks)
iii. Calculate the mass by volume percent (W/V) of NaCl in sea water. (4 Marks)
Lowest first
ionization energy
…………………
…..
Intermediate
ionization energy
…………………
…..
Highest first
ionization energy
…………………
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11.(a) A 20.0 L container at 303 K holds a mixture of two gases with a total pressure of 5.00
...
here are 2.00 mol of Gas A in the mixture, how many moles of Gas B are present? (R = 0.0821 L • atm/(K • mol))
(b) The gas in a 250. mL piston experiences a change in pressure from 1.00 atm to 2.80 atm. What is the new volume (in mL) assuming the moles of gas and temperature are held constant?
(c) Small quantities of Oxygen can be produced by the decomposition of mercury(II) oxide as shown below. Typically, the oxygen gas is bubbled through water for collection and becomes saturated with water vapor. Atomic weight of HgO = 216.6 amu, Atomic weight of Oxygen = 32.00 amu)
2 HgO(s) → 2 Hg(ℓ) + O₂(g)
(i) Assuming that 3.05 grams of HgO was used in this reaction, determine the number of moles of oxygen gas formed.(According to the above chemical equation)
(ii) Assuming 310. 0 mL of Oxygen gas was collected at at 29°C, calculate the pressure of the Oxygen gas that was collected. (R = 0.0821 L • atm/(K • mol)
(iii) If the vapor pressure of water at this temperature equals to 0.042 atm, calculate the pressure reading of this experiment.
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12.1) Which of the following statements about scientific methods / theories is correct?
(1/0/0)
a) A scientific theory must be able to
...
a) A scientific theory must be able to be proven.
b) A scientific theory has been derived from known facts and always applies.
c) A scientific method should give different results depending on who performs the method.
d) Knowledge of our surroundings usually emerges through an interplay between theory and experiment.
2) The sides of a straight block are measured to 3,202 cm; 0.0012 cm and 11.2 cm, respectively. Calculate the volume of the straightening block and enter it with the correct number of value digits.
(2/0/0)
Number of words: 0
3) A 9.2 dm long and evenly thick rod rests on a support. 0.55 dm from one end, a dynamometer is hung so that the rod will hang horizontally. Then the dynamometer shows 4.4 N. How much does the bar weigh?
(1/1/0)
Number of words: 0
4) A bar AB that is homogeneous and evenly thick has a length of 2.70 m and is rotatable about an axis at A. The bar weighs 25 kg and is kept in equilibrium by a force F which has its point of attack in B. is 45 degrees. How big is the force F?
(1/1/0)
Saved!
25 * 9.82 = 245.5 N
Number of words: 6
5) A trolley rolls at a constant speed to the right. On the cart is an upward cannon that suddenly shoots a bullet. The carriage continues to the right with the same speed as before. Where does the bullet end up when it falls? For a detailed reasoning.
(1/1/1)
Number of words: 0
6) A river is 200 m wide. The water in the river flows at a speed of 2.5 m / s. A motorboat steers across the river at its maximum speed, which in stagnant water is 5.0 m / s. The boat is constantly heading perpendicular to the banks of the river. Where does the motorboat land on the other shore?
(2/0/0)
Number of words: 0
7) A ball with a mass of 2.0 hg moves at a constant speed in a circular path. The radius of the track is 1.5 m and it takes the ball 3.0 seconds to move one turn. How big is the centripetal force?
(1/1/0)
Number of words: 0
8) A bullet moves at a constant speed. Can we then safely say that the resultant of the forces acting on the bullet is zero? Motivate and discuss your answer.
(0/1/1)
Number of words: 0
9) A conductor is located between the poles of a permanent magnet. The current in the conductor goes in the direction of the plane of the paper (away from the reader). How is the force acting on the leader directed?
(1/0/0)
a) To the right of the figure
b) To the left in the figure
c) Downwards in the figure
d) Upwards in the figure
10) Protons enter horizontally from the left between two large metal plates at a speed v = 0.80 Mm / s. The plates are connected to a voltage source with the pole voltage U. Between the plates there is a homogeneous magnetic field with a flux density of 38 mT directed perpendicular to the plane of the paper. The distance between the plates is 1.5 cm. They want the protons to continue with unchanged direction and speed between the plates. Which of the plates should be connected to the positive pole of the voltage source and how large should the voltage U be?
(0/2/0)
Number of words: 0
11) The magnetic flux Φ through a 700-speed coil decreases linearly with time according to the diagram below. Calculate the voltage across the coil at time t = 1.0 ms.
12) The current in a coil with an inductance of 35 mH has a growth rate of 6.2 A / s at a given moment. What is the instantaneous value of the ems induced in the coil?
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13.What would be the concentration of 2.000g of HNO3 if it was dissolved in 2.000L of water in moles per
...
r litre?
What would have been the concentration of HNO3 AFTER the 0.1000g of Li was added and allowed to react with some of HNO3? (Hint - Lim XS Problem) What would have been the pH of your acid solution after the metal was added?
If you wanted to fill a rubber balloon to an internal volume of 5.000L and pressure of 140.0kPa in a 25.00C room with hydrogen gas from the reaction of your metal and acid (Li and HNO3), what is the minimum quantity in millilitres of an 8.000M solution of your acid you would need to generate enough hydrogen gas? (assume you have more than enough metal).
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22.You are sleeping on an air mattress, which forms a rectangular "box" shape. The length and width don't change, but
...
't change, but throughout the night the height of the mattress is decreasing. The rate at which it decreases varies over time: at the beginning it is just shrinking a tiny bit, but after a while it starts shrinking faster. If the height of the of the mattress follows the formula h=18-0.2x^2, where h is the height in inches and x is the time in hours, and the length of the mattress is always 74 inches, and the width of the air mattress is always 54 inches, please find the rate at which the VOLUME of the air mattress is changing after 2 hours. V ' =
cubic inches per hour after 2 hours. (Round to one decimal place, but take a picture of your work and send it to me if you're worried your answer might be slightly off.)
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37.5 (5 points) There is H3PO4 available in stock solution that has an assay of 77% and a density
...
cific gravity) of 1.24. What is the molarity of this solution?
Using this solution how would 1 L of 2N solution be made.
6 (5 points) H3BO3 is needed to neutralize 20 ML of a 2N solution of NaOH. How much of the acid should I put in 40 ML of the water to exactly neutralize this solution?
7 (6 points) Describe how to make the solutions below :
20% w/v Salt in water.
20% v/v alcohol in water
20% w/w NaCl in water.
8 (three points) I have 0.6 g/dl solution of NaOH. What is M? Whan is N?
9 (six points) There are 3000mL of 3M NaOH. How much of the following do I need to neutralize? (watch your M’s and N’s
a) 3M H3PO4
b) 2M H2SO4
c) 1M HCL
10 (20 points) The following solutions of NaOH are mixed together 20ML of 3N, 40mL of 2N, 60mL of 1N, 80 mL of 4N, and 100mL of 5N.
a) What is the volume and normality of the final solution?
b) How much 4M sulfuric acid would I need to neutralize?
c) How much stock solution of sulfuric acid with an assay of 77% and a specific gravity of 1.14 would I need?
d) How many grams of HCl would I have to put in a 300mL solution of HCl in water to neutralize?
11 (3 points) How much 5N solution can I make with 98 grams of H3PO4 ?
12 (5 points) How much 5N solution of H3AsO4 can I make with 57 mL of stock solution that is 84% assay and 1.14 specific gravity?
13 (5 points) If we have a 4N solution of HCl that has 0.03645g of HCl in the solution, how many microliters of solution do we have?
14 (10 points) If we have 66mL of a solution of concentrated NaOH that has an assay of 88% and a specific gravity of 1.24, how much 3N H3AsO4 can be neutralized?
15 (ten points) If I have 17 mL of a 20% w/v solution of NaOH and I want to neutralize with H2SO4 that is available in a 4% w/v solution, how much of this solution will be required.
16 (ten points)
a) I have an 12mL of Ba(Cl)2 that is 78% assay that contains 8 grams of Ba(Cl)2. What is the specific gravity?
b) How many Moles of Ba(Cl)2 are there?
c) If I have 80 grams of NaOH in a liter of solution that is of an unknown specific gravity, can I calculate molarity and what is it?
d) What is the difference between molarity and normality?
e) I have 77 ml of 77% salt in water. How much 11% can I make?
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