a solution of hydrochloric acid (HCl). The molarity of the HCl is unknown molarity. If 0.0250 L of the standard solution is used and this reacts with 25.00 mL of HCl, what is the molarity (mol L-1) of the HCl?
izontal. Its upper
end is connected to a wall by
a rope, and its lower end rests
on a rough, horizontal sur-
face. The coefficient of static
friction between the beam
and surface is ms. Assume
the angle u is such that the static friction force is at its
maximum value. (a) Draw a force diagram for the beam.
(b) Using the condition of rotational equilibrium,
find an expression for the tension T in the rope in
terms of m, g, and u. (c) Using the condition of trans-
lational equilibrium, find a second expression for T in
terms of ms, m, and g. (d) Using the results from parts
(a) through (c), obtain an expression for ms
L
u
Figure P12.16
Q/C
S
vertical component of this force. Now solve the same
problem from the force diagram from part (a) by com-
puting torques around the junction between the cable
and the beam at the right-hand end of the beam. Find
(e) the vertical component of the force exerted by the
pole on the beam, (f) the tension in the cable, and
(g) the horizontal component of the force exerted
by the pole on the beam. (h) Compare the solution
to parts (b) through (d) with the solution to parts
(e) through (g). Is either solution more accurate?
19. Sir Lost-a-Lot dons his armor and sets out from the
castle on his trusty steed (Fig. P12.19). Usually, the
drawbridge is lowered to a horizontal position so that
the end of the bridge rests on the stone ledge. Unfor-
tunately, Lost-a-Lot’s
squire didn’t lower the draw-
involv-
ing only the angle u. (e) What happens if the ladder
is lifted upward and its base is placed back on the
ground slightly to the left of its position in Figure
P12.16? Explain.
cific gravity) of 1.24. What is the molarity of this solution?
Using this solution how would 1 L of 2N solution be made.
6 (5 points) H3BO3 is needed to neutralize 20 ML of a 2N solution of NaOH. How much of the acid should I put in 40 ML of the water to exactly neutralize this solution?
7 (6 points) Describe how to make the solutions below :
20% w/v Salt in water.
20% v/v alcohol in water
20% w/w NaCl in water.
8 (three points) I have 0.6 g/dl solution of NaOH. What is M? Whan is N?
9 (six points) There are 3000mL of 3M NaOH. How much of the following do I need to neutralize? (watch your M’s and N’s
a) 3M H3PO4
b) 2M H2SO4
c) 1M HCL
10 (20 points) The following solutions of NaOH are mixed together 20ML of 3N, 40mL of 2N, 60mL of 1N, 80 mL of 4N, and 100mL of 5N.
a) What is the volume and normality of the final solution?
b) How much 4M sulfuric acid would I need to neutralize?
c) How much stock solution of sulfuric acid with an assay of 77% and a specific gravity of 1.14 would I need?
d) How many grams of HCl would I have to put in a 300mL solution of HCl in water to neutralize?
11 (3 points) How much 5N solution can I make with 98 grams of H3PO4 ?
12 (5 points) How much 5N solution of H3AsO4 can I make with 57 mL of stock solution that is 84% assay and 1.14 specific gravity?
13 (5 points) If we have a 4N solution of HCl that has 0.03645g of HCl in the solution, how many microliters of solution do we have?
14 (10 points) If we have 66mL of a solution of concentrated NaOH that has an assay of 88% and a specific gravity of 1.24, how much 3N H3AsO4 can be neutralized?
15 (ten points) If I have 17 mL of a 20% w/v solution of NaOH and I want to neutralize with H2SO4 that is available in a 4% w/v solution, how much of this solution will be required.
16 (ten points)
a) I have an 12mL of Ba(Cl)2 that is 78% assay that contains 8 grams of Ba(Cl)2. What is the specific gravity?
b) How many Moles of Ba(Cl)2 are there?
c) If I have 80 grams of NaOH in a liter of solution that is of an unknown specific gravity, can I calculate molarity and what is it?
d) What is the difference between molarity and normality?
e) I have 77 ml of 77% salt in water. How much 11% can I make?